Diamagnetism is the property of a substance to be repelled by a magnetic field. Interestingly enough, water shows this effect. We build a simple, but very sensitive detector to show this. We also show pyrolytic carbon that is so diamagnetic that it can float above magnets if they are arranged the right way.
Water is diamagnetic, meaning it's slightly repelled by a magnetic field. But in everyday life this is almost impossible to notice. We need to build a very sensitive detector to see it.
Just get a basin of water and float a styrofoam block in it. Styrofoam is very light and so even the small repulsive force of a test tube of water will have a noticeable push on it. Push the test tube of water into the center of the block and simply hold a strong neodymium magnet as close as possible to the tube without touching it. It's a very small force, but eventually the block will start moving away from the magnet.
Pyrolytic graphite, also called pyrolytic carbon, exhibits the same effect and can even be made to levitate on top of a magnet. A single magnet is unstable since the graphite will like to fall off the side. But having four magnets and arranging them like in the video will create a "void" in the center that the graphite "falls" into and remains stably levitated.
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https://www.youtube.com/watch?v=jyqOTJOJSoU
In this video we explore the science behind the well-known reaction of brake fluid and pool chlorine.
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https://www.youtube.com/watch?v=SSNPtuAcTm0
In this video we show how to make potassium chlorate from potassium chloride by electrolysis.
For the anode, carbon, platinum or mixed metal oxide works best. For the cathode, almost any metal can be used but titanium is preferred.
The electrodes are simply inserted into a solution of potassium chloride salt and a current is passed through. The anode is the positive connection while the cathode is the negative connection. The current should be adjusted to match the surface of the electrode. For carbon that's around 40ma/cm^2, for platinum 300ma/cm^2, for mixed metal oxide 200ma/cm^2. You can use less current for lower heating and wear but the production will take longer.
The electrolysis must be kept in a well ventilated area since it produces hydrogen gas as well as small amounts of chlorine gas.
As the reaction progresses the potassium chlorate will precipitate our and the potassium chloride will be depleted. This has the overall effect of lowering the solution concentration. Every so often the salts must be topped up. Saturated potassium chloride solution has a density of 1.16g/mL. I recommend adding more potassium chloride salt when the density drifts below 1.1g/mL
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https://www.youtube.com/watch?v=itAnVJ2vpHQ
In this video we make luminol from domestically available chemicals.
The process pretty complicated and dangerous at parts and so should only performed by, or under the direct supervision of, an experienced chemist.
First we obtain diethylhexyl phthalate by refluxing 50g of finely cut vinyl gloves in enough isopropanol to completely cover them for at least one hour, preferably three to four.
The alcohol solution of diethylhexyl phthalate is filtered and the supernatant is boiled until it reduces to half its volume. An equal amount of water along with 10g of sodium hydroxide is added and the mixture boiled for an hour. This causes the diethylhexyl phthalate to hydrolyze into phthalic acid and 2-ethylhexanol. After the solution cools it will phase separate into an aqueous layer containing disodium phthalate and an organic layer containing the alcohols.
Retaining just the aqueous layer, 25mL of 12 molar hydrochloric acid is added to precipitate the phthalic acid. Chilling may be necessary. The supernatant is discarded and the residue of wet phthalic acid is purified and converted into phthalic anhydride by heating it to 300 Celsius. First the water boils off and then the phthalic anhydride evaporates and condenses on the sides of the beaker. At this point a flask of cold water is placed over the beaker to allow the phthalic anhydride to deposit on it. Periodically the phthalic anhydride deposits are harvested until no more can be obtained.
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https://www.youtube.com/watch?v=58Ve69s0qD0
In this video we show how to make a Zinc Air Battery.
First you'll need to make a solution of 50g of sodium hydroxide in 150mL of water. Stir it until it completely dissolves. Be careful as it will heat up a lot. Set it aside to cool.
Now get a zinc sheet (we cut one out of a carbon zinc battery in a previous video: http://www.youtube.com/watch?v=knc1lSupAwQ) and attach a wire to it and attach another wire to some steel wool. We then wrap the steel wool with a paper towel to serve as a separator. The zinc is then wrapped around the paper towel/steel wool and the whole assembly is placed into a container. The steel wool has to be exposed to air to allow the oxygen to get in. The electrolyte of sodium hydroxide is added and the battery is ready.
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https://www.youtube.com/watch?v=OcGWbt1mcrc
In this video we're going to start a charcoal barbecue... with chemistry. Part of the "10 Party Tricks for 2014" mega collaboration: http://bit.ly/10CrazyPartyTricks
See the full playlist: http://bit.ly/MegaCollabPlaylist
All these YouTubers posted videos on their channels as well. Check out their original videos below;
Brusspup: http://bit.ly/Brusspup_GlowingIceCubes
Kipkay: http://bit.ly/Kipkay_StarSpangledHammock
Night Hawk In Light: http://bit.ly/NHIL_GiantBubbles
Steve Spangler: http://bit.ly/SteveSpangler_ScienceTr...
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https://www.youtube.com/watch?v=eRtaPlEcEUU
Glassware generously provided by http://www.alchemylabsupply.com/
By popular request, how to make Copper (II) Chloride.
The first and simplest method is to get hydrochloric acid of around ~20% concentration and add copper. Then bubble air through it using an aquarium pump. The oxygen in the air oxidizes the copper and reacts with the acid to produce copper chloride. Pretty much any concentration of acid can be used, but we recommend around 20% as there are considerably less fumes. A major drawback of this method is that it's VERY slow and can take days to produce useful quantities of copper chloride.
The second far faster method is to react hydrochloric acid and copper with an equal volume of hydrogen peroxide. The recommended concentration of acid is greater than 20% and the peroxide is equal or greater than 3%. In our video we used 200 mL 31% hydrochloric acid, 30g of copper and 200 mL of 6% hydrogen peroxide. This reaction only takes a few hours to finish.
For many applications like PCB etching or gold recovery from circuit boards, sulfate contamination is not a problem so the third method uses readily available copper sulfate. Just take the copper sulfate and add as much hydrochloric acid as necessary to dissolve it. This directly produces copper chloride that can be used for the previously mentioned application. It will be contaminated with sulfate ions but these have no effect.
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https://www.youtube.com/watch?v=V8mHiFYmlBc
Glassware generously provided by http://www.alchemylabsupply.com/
Use the discount code "copper" for a 5% discount.
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Burn Steel wool: https://www.youtube.com/watch?v=5MDH92VxPEQ
Make thermite: https://www.youtube.com/watch?v=RiF73l4PjyY
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https://www.youtube.com/watch?v=vPnqLSyoEy8
In this video we recover the gallium that was used to induce structural failure in various aluminum objects.
First, the aluminum is covered with about 10 times its mass in water and a stoichiometric amount (to the aluminum) of sodium hydroxide is added. So for 27 grams we add about 40 grams of sodium hydroxide. This reacts with the aluminum and converts it sodium aluminate. Most of the gallium will remain.
Eventually the alloy should liquefy as the gallium proportion increases due to the loss of aluminum. The solution is cooled and the alloy is allowed to solidify.
The alloy is then added to 10-30 times its mass of water and heated to near boiling. The remaining aluminum should be consumed by the reaction with water. Once the gallium stops bubbling it is allowed to cool.
The gallium obtained has bits of aluminum oxides and slag embedded in it and this can be removed by melting the gallium in a solution of 20% sulfuric acid.
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https://www.youtube.com/watch?v=sUSjWfBBu2Y